导师介绍

导师姓名

姚子健

导师性别

男

职务职称

副教授

所在院系

化工学院

一级学科

化学

二级学科

无机化学、有机化学

研究方向

配位化学、有机金属化学及有机合成化学

联系电话

电子邮箱

zjyao@sit.edu.cn

个人简介

2014年毕业于复旦大学化学系，获理学博士学位。随后赴美国New York University从事博士后研究，2015年9月进入上海应用技术大学工作。2016年被聘为硕士生导师。近五年以第一作者或通讯作者在J. Am. Chem. Soc., Coord. Chem. Rev., Inorg. Chem., Chem. Commun.,   Organometallics, Chem. Eur. J.和Dalton Trans等国际著名期刊上发表论文30余篇。申请中国发明专利10项。现作为项目负责人主持国家和省部级项目5项，2017年入选上海市晨光计划，2023年入选上海市曙光计划。

学习与工作经历

1.      国家自然科学基金面上项目，No.22271193，项目负责人

2.      上海市教委曙光计划，No.23SG51，项目负责人

3.      国家自然科学青年基金，No.21601125，项目负责人

4.      上海市自然科学基金，No.16ZR1435700，项目负责人

5.      上海市教委晨光计划，No.16CG64，项目负责人

6.      上海市高校优秀青年教师培养资助计划，项目负责人

7.      上海应用技术大学人才引进启动经费，项目负责人

科研工作与成果

1.      Heng Li, Ke Wang, Lin Yang, Yu-Zhou Luo, Zi-Jian Yao*. Half-sandwich ruthenium complexes with   acylhydrazone ligands: synthesis and catalytic activity in the N-alkylation   of hydrazides. Dalton Trans. 2024, 53, 2797?2806.

2.      Ke Wang, Heng Li, Lin Yang, Yu-Zhou Luo, Zi-Jian Yao*. Heterogeneous catalytic conversion of carbon   dioxide and epoxides to cyclic carbonates. Surfaces and Interfaces2024,   45, 103845.

3.      Lin Yang, Ai-Lin Guan, Zheng-Yang Xu, Zi-Jian Yao*. Cyclometalated Half-Sandwich Ruthenium Complexes:   Preparation, Structure, and Catalytic Synthesis of Phenolic Esters from Aryl   Halides without Using External CO under Air. Inorg. Chem.2023, 62, 18198?18208.

4.      Yang Wang, Yu-Zhou Luo*, Zhen-Jiang Liu*, Zi-Jian Yao*. Cationic N,S-chelate half-sandwich   iridiumcomplexes: synthesis, characterization, anticancer and antiplasmodial   activity. Biomater. Sci. 2023, 11, 7090–7098.

5.      Ke Wang, Heng Li, Lin Yang, Zhen-Jiang Liu*, Zi-Jian Yao*. Half-Sandwich Ruthenium Complexes with Hydrazone   Ligands: Preparation, Structure, and Catalytic Activity in Cyanosilylether   Synthesis under an Air Atmosphere. Inorg.   Chem.2023, 62, 9872?9881.

6.      Song Gao, Zhen-Jiang Liu, Yu-Zhou Luo*, Zi-Jian Yao*. Half-sandwich iridium complexes with hydrazone   ligands: preparation, structure, and catalytic synthesis of cyanosilylethers   under air. Dalton Trans. 2023, 52, 11104?11112.

7.      Yang Wang, Fang-Lei Zhang, Zhen-Jiang Liu, Zi-Jian Yao*. Half-Sandwich Iridium Complexes with Hydrazone   Ligands: Synthesis and Catalytic Activity in N-Alkylation of Anilines or   Nitroarenes with Alcohols via Hydrogen Autotransfer. Inorg. Chem.2022, 61, 10310?10320.

8.      Mengyin Xu, Yang Wang, Yifeng Zhou, Zi-Jian Yao*.N,N-Chelate nickel(II) complexes bearing Schiffbase   ligands as efficient hydrogenation catalysts for amine synthesis. J. Organomet. Chem.2022, 959, 122187.

9.      Wen Guo, Zhen-Jiang Liu, Fanhong Wu, Yu-Zhou Luo*, Zi-Jian Yao*. [NN]-Chelate nickel   complexes with Schiff base ligands: Synthesis, structure and catalytic   activity in green amidation reaction. App. Organomet. Chem.2022, 36, e6808.

10.  Yang Wang, Wen Guo, Ai-Lin Guan, Shuang Liu, Zi-Jian Yao.* Half-Sandwich Iridium Complexes Based on   β-Ketoamino Ligands: Preparation, Structure, and Catalytic Activity in Amide   Synthesis. Inorg. Chem.2021, 60, 11514?11520.

11.  Wen-Rui Lv, Rong-Jian Li, Zhen-Jiang Liu,* Yan Jin,* Zi-Jian Yao.* Synthesis, Structure,   and Catalytic Hydrogenation Activity of [NO]-Chelate Half-Sandwich Iridium   Complexes with Schiff Base Ligands. Inorg.   Chem.2021, 60, 8181?8188.

12.  Rong-Jian Li, Yang Wang, Yan Jin, Wei Deng, Zhen-Jiang Liu,* Zi-Jian Yao.* NHC Ligand-Based   Half-Sandwich Iridium Complexes: Synthesis, Structure and Catalytic Activity   in Acceptorless Dehydrogenation and Transfer Hydrogenation. New J. Chem.2021, 45, 19002?19010.

13.  Rong-Jian Li, Chun Ling, Wen-Rui Lv, Wei Deng, Zi-Jian Yao.* Cyclometalated   Half-Sandwich Iridium(III) Complexes: Synthesis, Structure and Diverse   Catalytic Activity in Imine Synthesis Using Air as Oxidant. Inorg. Chem.2021, 60, 5153?5162.

14.  Yong-Xu Jin, Wei Deng, Zhen-Jiang Liu, Zi-Jian Yao*. Synthesis and Optoelectronic Properties of Cationic   Iridium(III) Complexes with o?Carborane- Based 2?Phenyl Benzothiazole   Ligands. Inorg. Chem. 2021,   60, 2756?2763.

15.  Xue-Jing Yun, Chun Ling, Wei Deng, Zhen-Jiang Liu, Zi-Jian Yao*. Half-Sandwich Ru(II)   Complexes with N,O-Chelate Ligands: Diverse Catalytic Activity for Amine   Synthesis in Water. Organometallics2020, 39, 3830?3838.

16.  Xiao-Nan Fan, Wei Deng, Zhen-Jiang Liu, Zi-Jian Yao*. Half-Sandwich Iridium Complexes for One-Pot   Synthesis of Amides: Preparation, Structure and Diverse Catalytic Activity. Inorg. Chem.2020, 59, 16582?16590.

17.  Xue-Jing Yun, Jing-Wei Zhu, Yan Jin, Wei Deng, Zi-Jian Yao*. Half-Sandwich Ruthenium   Complexes for One-Pot Synthesis of Quinolines and Tetrahydroquinolines:   Diverse Catalytic Activity in the Coupled Cyclization and Hydrogenation   Process. Inorg. Chem.2020, 59, 7841?7851.

18.  Xiao-Nan Fan, Hui-Dan Ou, Wei Deng, Zi-Jian Yao*. Air-Stable Half-Sandwich Iridium Complexes as   Aerobic Oxidation Catalysts for Imine Synthesis. Inorg. Chem.2020, 59, 4800?4809.

19.  Jing-Wei Zhu, Hui-Dan Ou, Niwei Xu, Wei Deng*, Zi-Jian Yao*. Ruthenium-based phosphorescent probe for selective   and naked-eye detection of cyanide in aqueous media. Dyes and Pigments.2020,   176, 108196.

20.  Nan Lin, Hui-Dan Ou, Qiyan Xu*, Yan Jin*, Wei Deng, Zi-Jian Yao*. An Efficient Probe of   Cyclometallated Phosphorescent Iridium Complex for Selective Detection of   Cyanide. ACS Omega. 2020, 5, 4636?4645. (Front cover)

21.  Zi-Jian Yao*, Jing-Wei Zhu, Nan Lin, Xin-Chao Qiao, Wei Deng*.   Catalytic Hydrogenation of Carbonyl and Nitro Compounds Using [NO]-chelate   Half-Sandwich Ruthenium Catalyst. Dalton Trans. 2019, 48, 7158?7166.

22.  Peng Li, Jin-Bao Liu, Sheng Han, Wei Deng*, Zi-Jian Yao*. Half-sandwich Ir(III) and Rh(III) complexes as   catalysts for water oxidation with double-site. App. Organomet. Chem.2019, 33, e5040.

23.  Xin-Chao Qiao, Dan-Chen Qiu, Nan Lin, Jing-Wei Zhu, Wei Deng, Zi-Jian Yao*. Half-Sandwich   Ruthenium-Based Versatile Catalyst for Both Alcohol Oxidation and Catalytic   Hydrogenation of Carbonyl Compounds in Aqueous Media. App. Organomet. Chem.2019, 33, e4875.

24.  Peng Li, Yi-Mei Xu, Wei Deng*,   Zi-Jian Yao*. Self-assembly of   supramolecular coordination complexes based on half-sandwich metal corner   with tunable host cavities. J. Organomet. Chem. 2019, 884,   36?43.

25.  Zi-Jian Yao*, Nan Lin, Xin-Chao Qiao, Jing-Wei Zhu, Wei Deng*. Cyclometalated   Half-Sandwich Iridium Complex for Catalytic Hydrogenation of Imines and   Quinolines. Organometallics2018, 37, 3883.

26.  Zi-Jian Yao*, Peng Li, Kuan Li, Wei Deng*. Synthesis, structure and catalytic polymerization activity of half‐sandwich   cyclometallated iridium complexes. App.   Organomet. Chem.2018, 32, e4239.

27.    Zi-Jian Yao*, Kuan Li, Peng Li, Wei   Deng*. Mononuclear half-sandwich   iridium and rhodium complexes through C?H activation: Synthesis,   characterization and catalytic activity. J. Organomet. Chem. 2017,   846, 208.

28.  Yi-Mei. Xu, Kuan. Li, Yuhong.   Wang, Wei Deng, Zi-Jian Yao*. Mononuclear Nickel(II) Complexes with Schiff Base Ligands: Synthesis,   Characterization, and Catalytic Activity in Norbornene Polymerization. Polymers2017, 9, 105.

29.  Zi-Jian Yao*, Wei Deng*. Half-sandwich late transition metal complexes based   on functionalized carborane ligands. Coord. Chem. Rev. 2016, 309,   21.

30.  Zi-Jian Yao,* Kuan Li, Jian-Yong Zhang and Wei Deng*. [NO]- and   [NN]-coordination mode rhodium complexes based on a flexible ligand:   synthesis, reactivity and catalytic activity. New J. Chem.2016, 40, 8753.

31.  Zi-Jian Yao*, Shibin Hong, Wei Zhang, Meiyan Liu, Wei Deng*.   Transition-metal-free hydroboration of terminal alkynes activated by base. Tetrahedron Lett.2016, 57, 1.

32.  Kuan Li, Zi-Jian Yao*,   Wei Deng*. Synthesis, Reactivity and Application of Diverse   Carboranylphosphine-Based Ligands. Curr.   Org. Synth. 2016, 13, 504.

33.  Zi-Jian Yao*, Kuan Li, Jian-Yong Zhang, Yuhong Wang, Wei Deng*. Synthesis,   characterization and polymerization activity of copper complexes with N,   O-chelate ligands. Inorg. Chem. Acta.2016, 450, 118.

34.  Zi-Jian Yao, Wei-Bin Yu, Yue-Jian Lin,   Sheng-Li Huang, Zhen-Hua Li and Guo-Xin Jin*. Iridium-Mediated Regioselective   B?H/C?H Activation of Carborane Cage: A Facile Synthetic Route to   Metallacycles with a Carborane Backbone. J. Am. Chem. Soc. 2014,   136, 2825.

35.  Zi-Jian Yao and Guo-Xin Jin*.   Transition Metal Complexes Based on Carboranyl Ligands Containing N, P, S   Donors: Synthesis, Reactivity and Application. Coord. Chem. Rev. 2013,   257, 2522.

社会学术团体兼职

中国化学会会员，美国化学会会员

主要研究方向

近3年指导研究生的就业情况

累计指导研究生25名，其中，在校生8名。