导师姓名

蔡夫锋

导师性别

男

职务职称

副教授

所在院系

化学与环境工程学院

一级学科

化学工程与技术

二级学科

化学工程

研究方向

能源化学催化与转化

联系电话

021-60877223

电子邮箱

caiff@sit.edu.cn

个人简介

蔡夫锋，男，工学博士，副教授，主要从事甲醇/甲烷重整、甘油氢解等方面的研究工作。紧密围绕C-O键与C-H键高效活化开展一系列相关的能源化学基础研究及催化剂研发。作为负责人主持科研项目6项，包括国家自然科学青年基金，上海市青年科技扬帆计划等；发表SCI学术论文31篇；申请发明专利5项，其中授权发明专利2项。

学习与工作经历

学习经历：

2014.03-2017.04，东南大学，    专业：化学工程与技术，工学博士

2010.09-2013.07，北京化工大学，专业：化学工程与技术，工学硕士

2006.09-2010.07，北京化工大学，专业：化学工程与工艺，工学学士

工作经历：

2021.01-至今，   上海应用技术大学，副教授

2017.05-2020.12，中国科学院上海高等研究院，助理研究员

2013.07-2013.12，中国热带农业科学院分析测试中心，质检员

科研工作与成果

主持的主要科研项目：

1.国家自然科学青年基金，锌掺杂对铂/碳化钼催化剂的影响机制及催化甲醇水蒸气重整制氢作用机理研究，项目负责人，2019.01-2021.12。

2. 上海市青年科技英才扬帆计划项目，基于碳化物纳米催化剂的可控制备及其催化甲醇重整制氢性能研究，项目负责人，2018.05-2021.04。

3. 企业横向项目，挂烫机铜/钛合金发热器加热效率与稳定性优化研究，项目负责人，2023.10-2024.10。

发表的主要研究成果：

发表SCI学术论文31篇，申请发明专利5项，授权发明专利2项，具体如下：

(1) Fufeng Cai,* Yanjiao Guo, Guomin Xiao. Selective hydrogenolysis of glycerol to 1,2-propanediol   over Co-Al₂O₃ catalysts in batch and continuous reactors.   Chemical Engineering and Technology, 2023, 46, 256–263.

(2) Fufeng Cai,*   Yanjiao Guo, Jessica Juweriah Ibrahim, Jun Zhang,* Yuhan Sun. A highly active   and stable Pd/MoC catalyst for hydrogen production from methanol   decomposition. Applied Catalysis B: Environmental, 2021, 299, 120648.

(3) Wenbo Kong, Yu Fu, Lei Shi, Shenggang Li, Evgeny Vovk, Xiaohong   Zhou, Rui Si, Bingrong Pan, Changkun Yuan, Shuqing Li, Fufeng Cai, He Zhu, Jun Zhang,* Yong Yang,* Yuhan Sun.*   Nickel nanoparticles with interfacial confinement mimic noble metal catalyst   in methane dry reforming. Applied Catalysis B: Environmental, 2021, 285,   119837.

(4) Jie Hao, Fufeng Cai,   Jiyang Wang, Yu Fu, Jun Zhang,* Yuhan Sun.* The effect of oxygen vacancy of   alkaline-earth metal Sr doped Sm₂Zr₂O₇   catalysts in the oxidative coupling of methane. Chemical Physics Letters,   2021, 771, 138562.

(5) Fufeng Cai,   Jessica Juweriah Ibrahim, Yu Fu, Wenbo Kong, Jun Zhang,* Yuhan Sun.*   Low-temperature hydrogen production from methanol steam reforming on   Zn-modified Pt/MoC catalysts. Applied Catalysis B: Environmental, 2020, 264,   118500.

(6) Fufeng Cai,*   Jessica Juweriah Ibrahim, Yu Fu, Wenbo Kong, Shuqing Li, Jun Zhang,* Yuhan   Sun. Methanol steam reforming over ZnPt/MoC catalysts: effects of hydrogen   treatment. Industrial & Engineering Chemistry Research, 2020, 59, 18756?18770.

(7) Shuqing Li, Yu Fu, Wenbo Kong, Bingrong Pan, Changkun Yuan, Fufeng Cai, He Zhu, Jun Zhan,*   Yuhan Sun.* Dually confined Ni nanoparticles by room-temperature degradation   of AlN for dry reforming of methane. Applied Catalysis B: Environmental, 2020,   277, 118921.

(8) Feikai Jin, Yu Fu, Wenbo Kong, Jiyang Wang, Fufeng Cai, Changkun Yuan, Bingrong Pan, Jun Zhang,*   Yuhan, Sun.* Stable trimetallic NiFeCu catalysts with high carbon resistance   for dry reforming of methane. ChemPlusChem, 2020, 85, 1120-1128.

(9) Feikai Jin, Yu Fu, Wenbo Kong, Jiyang Wang, Fufeng Cai, Jun Zhang, Jiaqiang Xu.* Dry reforming of   methane over trimetallic NiFeCu alloy catalysts. Chemical Physics Letters,   2020, 750, 137491.

(10) Fufeng Cai,   Peijing Lu, Jessica Juweriah Ibrahim, Yu Fu, Jun Zhang,* Yuhan Sun.*   Investigation of the role of Nb on Pd–Zr–Zn catalyst in methanol steam   reforming for hydrogen production. International Journal of Hydrogen Energy,   2019, 44, 11717–11733.

(11) Fufeng Cai,*   Feikai Jin, Jie Hao, Guomin Xiao. Selective hydrogenolysis of glycerol to   1,2-propanediol on Nb-modified Pd?Zr?Al catalysts. Catalysis Communications,   2019, 131, 105801.

(12) Wenbo Kong, Yu Fu, Cairu Guan, Bingrong Pan, Changkun Yuan, Shuqing   Li, Fufeng Cai, Jun Zhang,*   Yuhan Sun.* Facile Synthesis of Highly Coking-Resistant and Active   Nickel-Based Catalyst for Low-Temperature CO₂ Reforming of   Methane.Energy Technology,   2019, 7, 1900521.

(13) Peijing Lu, Fufeng Cai,   Jun Zhang, Yuyu Liu,* Yuhan Sun. Hydrogen production from methanol steam reforming   over B-modified CuZnAlO_x   catalysts. Journal of Fuel Chemistry and Technology, 2019, 47, 791–798

(14) Fufeng Cai,*   Xianghai Song, Yuanfeng Wu, Jun Zhang,* Guomin Xiao.* Selective   hydrogenolysis of glycerol over acid-modified Co-Al catalysts in a fixed-bed   flow reactor. ACS Sustainable Chemistry & Engineering, 2018, 6, 110–118.

(15) Fufeng Cai,*   Donghui Pan, Jessica Juweriah Ibrahim, Jun Zhang,* Guomin Xiao.   Hydrogenolysis of glycerol over supported bimetallic Ni/Cu catalysts with and   without external hydrogen addition in a fixed-bed flow reactor. Applied   Catalysis A, General, 2018, 564, 172–182.

(16) Wei Zhu, Pengxin Shen, Yuan Wang, Fufeng Cai, Guomin Xiao.* Hydrogenolysis of glycerol to   propanediols over heteropolyacids promoted AgCu/Al₂O₃   catalysts. Chemical Papers, 2017, 71, 1645–1655.

(17) Wei Zhu, Fufeng Cai,   Yuan Wang, Shengya Sang, Guomin Xiao.* Hydrogenolysis of glycerol to   propanediols over supported Ag-Cu catalysts. Chemical Papers, 2017, 71,   763–773.

(18) Xiang Song, Yuanfeng Wu, Donghui Pan, Fufeng Cai, Guomin Xiao.* Carbon nitride as efficient   catalyst for chemical fixation of CO₂ into chloropropene   carbonate: Promotion effect of Cl in epichlorohydrin. Molecular Catalysis,   2017, 436, 228–236.

(19) Yuanfeng Wu, Xianghai Song, Fufeng   Cai, Guomin Xiao.* Synthesis of glycerol carbonate from glycerol and   diethyl carbonate over Ce-NiO catalyst: The role of multiphase Ni. Journal of   Alloys and Compounds, 2017, 720, 360–368.

(20) Xianghai Song, Yuanfeng Wu, Fufeng   Cai, Donghui Pan, Guomin Xiao.* High-efficiency and low-cost Li/ZnO   catalysts for synthesis of glycerol carbonate from glycerol   transesterification: The role of Li and ZnO interaction. Applied Catalysis A:   General, 2017, 532, 77–85

(21) Fufeng Cai, Wei   Zhu, Guomin Xiao.* Promoting effect of zirconium oxide on Cu-Al₂O₃   catalyst for the hydrogenolysis of glycerol to 1,2-propanediol. Catalysis   Science & Technology, 2016, 6, 4889–4900.

(22) Fufeng Cai,   Guomin Xiao.* Promoting effect of Ce on a Cu-Co-Al catalyst for the   hydrogenolysis of glycerol to 1,2-propanediol. Catalysis Science &   Technology, 2016, 6, 5656–5667.

(23) Fufeng Cai, Min   Zhao, Yuan Wang, Fei Wang, Guomin Xiao.* Phosphoric-based ionic liquids as   solvents to separate the azeotropic mixture ethanol and hexane. Journal of   Chemical Thermodynamics, 2015, 81, 177–183.

(24) Fufeng Cai, Wei   Zhu, Jessica Juweriah Ibrahim, Guomin Xiao.* Liquid extraction of polyhydric   alcohols from water using [A336][SCN] as a solvent. Journal of Chemical   Thermodynamics, 2015, 89, 35–40.

(25) Fufeng Cai, Guomin   Xiao.* Liquid–liquid extraction of methanol from alkanes using   dialkylphosphate-based ionic liquids as solvents. Journal of Chemical   Thermodynamics, 2015, 87, 110–116.

(26) Fufeng Cai,   Guomin Xiao.* Liquid–liquid equilibria of ternary systems ethanol + heptane +   phosphoric-based ionic liquids. Fluid Phase Equilibria, 2015, 386, 155–161.

(27) Fufeng Cai,   Jessica Juweriah Ibrahim, Lei Niu, Wei Xu, Guomin Xiao.* Liquid–liquid   equilibrium for ternary system methanol + methyl acetate +   1,3-dimethylimidazolium dimethylphosphate at several temperatures and   atmospheric pressure. Journal of Chemical & Engineering Data, 2015, 60,   57?64.

(28) Fufeng Cai, Wei   Zhu, Yanbin Wang, Tongzhen Wang, Guomin Xiao.* Dialkylphosphate-based ionic   liquids as solvents to extract toluene from heptane. Journal of Chemical   & Engineering Data, 2015, 60, 1776?1780.

(29) Fufeng Cai,   Jessica Juweriah Ibrahim, Lijing Gao, Ruiping Wei, Guomin Xiao.* A study on   the liquid–liquid equilibrium of 1-alkyl-3-methyl-imidazolium   dialkylphosphate with methanol and dimethyl carbonate. Fluid Phase   Equilibria, 2014, 382, 254–259.

(30) Fufeng Cai,   Xinying Wu, Chang Chen, Xiaochun Chen, Charles Asumana, Md Razibul Haque,   Guangren Yu.* Isobaric vapor–liquid equilibrium for methanol + dimethyl   carbonate + phosphoric-based ionic liquids. Fluid Phase Equilibria, 2013,   352, 47–53.

(31) Xiaochun Chen, Fufeng Cai,   Xinying Wu, Charles Asumana, and Guangren Yu.* Isobaric vapor?liquid   equilibrium for methanol + dimethyl carbonate + 1-butyl-3- methylimidazolium   dibutylphosphate. Journal of Chemical & Engineering Data, 2013, 58,   1186?1192.

(32) 张军, 蔡夫锋, 孙予罕. 一种甲醇重整制氢催化剂及其制备方法, 中国发明专利, 授权公告号:CN 110075889 B.

(33) 张军, 蔡夫锋, 孙予罕. 一种铜基催化剂、制备方法及应用, 中国发明专利, 授权公告号:CN 110787809 B.

(34) 蔡夫锋,唐京池, 郭艳娇, 毛东森, 吴贵升, 俞俊, 薛招腾. 一种碳化钼基催化剂及其制备方法与应用, 中国发明专利, 专利申请号2024100549686.

(35) 毛东森, 汪旭东, 薛招腾, 孟涛, 俞俊, 郭晓明, 吴贵升, 蔡夫锋. 一种有机碱改性SAPO-34分子筛及其制备和应用, 中国发明专利, 申请公开号CN115178293A.

(36) 肖国民, 蔡夫锋. 一种用于甘油氢解制备1,3-丙二醇的催化剂, 中国发明专利, 申请公开号CN 105344357 A.

社会学术团体兼职

中国化学会会员。

主要研究方向

(1) 甲醇、乙醇、甘油等生物质基产品重整制氢研究。

(2) 甲烷、二氧化碳等资源小分子催化转化利用研究。

近3年指导研究生的就业情况

指导硕士研究生6名。